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Research Article Open Access

Functionalization of polyallylamine on graphene oxide

Pooja Saini1, Khobaib1, Prikshit Gautam1, Manjari Singh2, Ram P. Tandon1,

S. P. Singh2, Ajit K. Mahapatro1*

1Department of Physics and Astrophysics, University of Delhi, Delhi, 110007, India

2Department of Nanomedicines and Cancer Physics, National Physical Laboratory,

Dr. K. S. Krishnan Marg, New Delhi, 110012, India

Adv. Mater. Proc., 2017, 2 (3), 209-212

DOI: 10.5185/amp.2016/3015

Publication Date (Web):05 March 2017

Copyright © IAAM-VBRI Press

Abstract


Abstract

This work explains the functionalization of polyallylamine (PAA) on the graphene oxide (GO) sheets following a chemical route. The resulting GO-PAA complex is characterized by using various imaging and analytical tools. In the Raman spectroscopy for both the GO and GO-PAA, the appearance of D and G characteristic bands correspond to the sp2 and sp3 contents, respectively, in the carbon sheets. The observation of lowered D/G peak intensity ratio of these peaks from 1.3 for GO to 1.1 for GO-PAA indicates the lowering of the D favored sp2 content in the GO sheet after PAA functionalization. In the Fourier transform infra-red spectroscopy, the disappearance of the vibrational modes for ketone and carboxyl groups, and appearance of the amine (-NH) group confirms the chemical interaction of GO and PAA triggered with the -NH group of PAA interacting with the oxygen contained hydroxyl, epoxy, and carboxylic groups of the GO sheets to form the GO-PAA complex. Scanning electron microscopy imaging indicates opaque layers with no distinction of flakes after PAA functionalization. Copyright © 2017 VBRI Press

Keywords


Graphene oxide (GO), Polyallylamine (PAA), GO surface functionalization, GO-PAA complex, functional groups