Impedance Spectroscopy And Conductivity Studies Of CdCl2 Doped Polymer Electrolyte

Mayank Pandey1, Girish M. Joshi1*, Kalim Deshmukh1, Jamil Ahmad

1Polymer Nanocomposite Laboratory, Material Physics Division, School of Advanced Sciences, VIT University,Vellore-632014, TN, India

2Department of Chemical Engineering, University of Engineering and Technology, Peshawar, Pakistan

Adv. Mater. Lett., 2015, 6 (2), pp 165-171

DOI: 10.5185/amlett.2015.5639

Publication Date (Web): Feb 08, 2015

E-mail: varadgm@gmail.com

Abstract


Polyvinyl alcohol (PVA) and Polyvinyl Pyrrolidone (PVP) based polymer electrolytes for different loading wt% of CdCl2 were prepared by solution casting. The structural complexation was confirmed and interlayer spacing (d) was evaluated by using X-ray diffraction (XRD) study. The chemical bonding between polymer and salt was identified by using Fourier transform infrared spectroscopy (FTIR) technique. The FTIR peak at 3402.43 cm-1 in addition of PVP in PVA/CdCl2 composite demonstrates the grafting between two polymers. The presence of ionic bright channels and variation in morphology for different loading wt% of CdCl2 was confirmed by scanning electron microscope (SEM) and was also verified by Atomic force microscopy (AFM) micrographs. The analysis of impedance spectroscopy represented by semicircular pattern is driven by conduction mechanism and correlated with electrical conductivity. The enhanced AC conductivity of polymer electrolyte is directly proportional to frequency (50Hz-1MHz). The maximum value of DC conductivity 1.65x10-5 S/m evaluated from Arrhenius plots and attribute to high mobility of free charges at higher temperature. The evaluated results of structural, morphological and electrical properties of present composites make the present research good for electrochemical devices.

Keywords

Impedance spectroscopy, AC and DC conductivity, XRD, FTIR, SEM, AFM.

Current Issue

Celebrating 10th Years of Diamond Open Access Publishing in Advanced Materials  


Cerebral Oxygenation Studies Through Near Infrared Spectroscopy: A Review


Analysis of Fine Sulfoaluminate Cement by Strength and Thermogravimetric Analysis


Characterization of the Interfacial Surface Energy for Composite Electrical Conduction Measurements using Two Full Range Percolation Threshold Models


Quantitative Detect of Fatigue of Membrane of Erythrocyte in Uniform Shear Field


Ecofriendly-developed Polyacrylic Acid-coated Magnetic Nanoparticles as Catalysts in Photo-fenton Processes


Evaluation of Drug Interactions with Medications Prescribed to Ambulatory Patients with Metabolic Syndrome in Urban Area


Fiber-reinforced Cementitious Composite: Sensitivity Analysis and Parameter Identification 


Evaluation of Drug Utilization Patterns Based on World Health Organization Drug use Indicators at Outpatients Clinics


Are Quantitatively Micro-machined Scaffolds Effective for Cell Technology?


Synthesis and Characterization of Gold Nanoparticles from Lobelia Nicotianifolia Leaf Extract and its Biological Activities


Advanced Oxidations of Tartrazine Azo-dye


Antifungal Activity of Salvia jordanii Against the Oral Thrush Caused by the Cosmopolitan Yeast Candida albicans among Elderly Diabetic Type 2 patients


Previous issues

Advanced Materials Congress Celebrating 10th Years of Establishment

Secure Management of Networked Batteries for Building Integrated Photovoltaics (BIPV) Systems  

The Cause of 100-year Low Carbonated Concrete of the Bridge 

Organic Montmorillonite Intercalated Nano-composites Prevent Post-Surgical Associated Infections

Morphology/tensile Performance Relationship for LLDPE/PP Double Gated Injected Blends

Preparation and Characterization of Nickel Ferrite Nanoparticles via Sol-gel Method

Nitrogen-doped Diamond Nanowire Gas Sensor for the Detection of Methane

Manufacture of Functional Open-cell Al Foams with Recycled Al Scraps using NaCl Ball Space Holder 

Vilsmeier-Haack Transformations under Non Classical Conditions

New Application of Highly Vesicular Basalt from Jabel Isbil Volcano (Dhamar-Rada'a Volcanic Field), Yemen

An Assessment of Tribological Characteristics under different Operating Condition

Functional Bi Coatings as A Perspective Material for Radiation Shields Production against Electron Radiation

Effects of Silica Modified NiFe2O4 on the Dielectric and Electrical Properties of NiFe2O4 filled Poly (methyl methacrylate) Composites

Upcoming Congress

Knowledge Experience at Sea TM