Solvent Free Selective Isomerization Of p-diethylbenzene To m-diethylbenzene Using Modified Hβ Zeolites
Mahesh S. Edake, Shriniwas D. Samant*
Organic Chemistry Research Laboratory, Institute of Chemical Technology, N.M. Parekh Road, Matunga, Mumbai 400 019, India
Adv. Mater. Lett., 2014, 5 (10), pp 550-556
DOI: 10.5185/amlett.2014.2586
Publication Date (Web): Nov 09, 2014
Copyright © 2019 VBRI Press
E-mail: samantsd@yahoo.com
Solvent free and selective isomerization of p-diethylbenzene (p-DEB) to m-diethylbenzene (m-DEB) was carried out using metal modified zeolite Hβ at high temperature. The metal modification of Hβ catalyst was carried out by using typical Lewis acidic cations Al3+, Fe3+, Ti4+, Sn4+ and Sb3+. The catalysts were characterized by XRD, FE-SEM, HR-TEM, FT-IR, N2-desorption (BET), ICP-AES, NH3-TPD, pyridine-IR, and TGA techniques for structure, morphology, acidity and stability. Particle size of the crystallites was determined by HR-TEM and the size was in the range of 15 - 35 nm. At 250oC, Al-Hβ, Fe-Hβ and Ti-Hβ catalysts showed 69 - 75% conversion of p-DEB with 43 - 51% selectivity towards m-DEB. This process is a greener alternative to the classical AlCl3 process. Further, such an isomerization would make the styrene manufacture more economic.
Zeolite H&beta, diethylbenzene, isomerization, heterogeneous catalysis, cation exchange
Current Global Scenario of Electric Vehicles
Review on Detection of Phenol in Water
Investigating the Machinability of Metallic Matrix Composites Reinforced by Carbon Nanotubes: A Review
Photocatalytic ZnO based PES Membranes for AOP Water Treatments under UV and Sunlight
Plasma Activated Water as a Source of Nitrogen for Algae Growth
Digital Light Processing (DLP) 3D Printing of Polyethylene Glycol (PEG) Biopolymer, Commercially available Ultra-High and Tough (UHT) Resin and Maghemite (γ-Fe2O3) Nanoparticles Mixture for Tissue Engineering Scaffold Application
Fabrication of Nanoparticle Embedded Polymeric Microbeads as an Efficient Drug Delivery System
Micro/Nanostructured Papers from Bagasse Pulp Reinforced by Nanofibrillated Cellulose from different Agro-Waste Sources
Structural, Optical and Magnetic Properties of Pristine, (Mn, Al) co-doped ZnO Nanocrystallites Synthesized via co-Precipitation Method
Nanosecond Laser Surface Patterning of Ti6Al4V Bio-alloy for Improved Biological Performance
Synthesis of Cu2O/Ag Composite Nanocubes with Promising Photoluminescence and Photodegradation Activity over Methylene Blue Dye
Locally available Clays of Bangladesh as a Replacement of imported Clays for Ceramic Industries
Green Synthesis and Characterization of Silver Nanoparticles using Cassia auriculata Leaves Extract and Its Efficacy as A Potential Antibacterial and Cytotoxic Effect
Wearable Healthcare Devices
Nano-Graphene and Its Derivatives for Fabrication of Flexible Electronic Devices: A Quick Review
Natural Fibers as Viable Sources for the Development of Structural, Semi-Structural, and Technological Materials – A Review
Geometrical Characterization of Wire-and-Arc Additive Manufactured Steel Element
Plasma Activated Water Generation and its Application in Agriculture
Development of Advanced Electrode Materials on Porous Silicon for Micropower Formic Acid-Oxygen Fuel Cells
Water Management within Tragacanth gum-g-polyitaconic Acid Hydrogels
Synthesis and Characterization of Humic Acid-coated Fe3O4 Nanoparticles for Methylene Blue Adsorption Activity
Synthesis and characterization of thermally stable flame retardant thermoplastic polyphosphazenes
Synthesis of Rod-coil Molecules bearing Oligo-Phenylene Vinylene Motifs: Effect of PEO Chain Lengths on the Evolution of Nanostructures Morphology and their Photophysical Properties
Dielectric Properties of Cu based Polymeric Composites in X-band of Microwave Frequency
Critical Association Concentration of Dansyl-Poly (acrylic acid) Synthetized by Redox Polymerization Followed by an Esterification in Aqueous Solution: Spectrophotometric and Tensiometric Studies
Influence of Iron Doping on Structural and Optical Properties of Nickel Oxide Nanoparticles
Copyright ©2010-2019 VBRI Press
Full Article