P.G and Research Department of Chemistry, V.O. Chidambaram College, Thoothukudi 628008, Tamil Nadu, India
Adv. Mater. Lett., 2013, Current Issue , 4 (9), pp 688-695
DOI: 10.5185/amlett.2013.1406
Publication Date (Web): Aug 10, 2013
Copyright © IAAM-VBRI Press
E-mail: peteramaldhast@yahoo.co.in
A new route for the utilization of fly ash has been formulated. X-type zeolite has been synthesized from fly ash by alkali fusion followed by hydrothermal treatment. Ascorbic acid was used as a ligand for the synthesis of metal complexes of copper, nickel and vanadium encapsulated in the super cages of fly ash based zeolite (FAZ) by flexible ligand method and characterized by FTIR, XRD, Atomic Absorption Spectrometry (AAS), Ultra Violet–Visible spectroscopy and Thermo gravimetric analysis (TGA). The additional peaks corresponding to that of the complex have been observed which confirms the loading of the metal complexes in the zeolite cavities. The shifting of C=C-O stretching frequency found at 682 cm-1 in ascorbic acid to 601 cm-1 confirms the co-ordination of the ligand resulting in the formation of the metal complex. The thermo grams show deflation in three regions corresponding to the loss of the intra-zeolite water, metal complexes and the structural –OH group respectively. The catalytic activity of these complexes towards the liquid phase hydroxylation of phenol with hydrogen peroxide has been established. The extent of the reaction as a function of time has been investigated. Vanadium-ascorbate complex had the highest conversion of 78%. The product was identified as hydroquinol by GC-MS. This study reports a highly attractive catalytic method for the preparation of hydroquinol from phenol using aqueous hydrogen peroxide as the oxidising agent which is industrially significant.
Fly ash, zeolite, hydrothermal treatment, flexible ligand method, hydroxylation of phenol.
Advanced Healthcare Biomaterials
Piezoelectric Alternative Energy Sources as a Part of the Global Energy Concerns – Future Prospects in the Science and Market
Rectify the Injury-Induced Microenvironment Imbalance in Peripheral Nerve Repair
A Mini Review on Biodegradable Magnesium Alloy Vascular Stent
Prospective Applications of Marine Oriented Materials in the Repair of Peripheral Nerve Injury
Design and Implementation of Dynamic FPAA Based Interface Circuit for Thin Film Lead-Free Piezoelectric Sensors
An Аpproach for Nanostructuring of Piezoelectric Materials by Template-assisted Growth in Porous Aluminum Oxide
Study of Sputtered Barium Strontium Titanate Films for Energy Harvesting Applications
The Effect of Bias on Properties of DLC Coatings for Artificial Joints
Fabrication of Tens-micron-sized Functionalized Polystyrene Microspheres for Utilization in Chiral Drug Isolation
COVID-19: A Mechanistic Approach to Understand the Detrimental Consequences for Vaccine Development and Perspectives
Contribution of Nanotechnology in Animal and Human Health Care
Numerical and Analytical study on Axial Compression behaviour of Pultruded GFRP members
Optical Characterization of Double Perovskite Ba2FeNbO6 Powders Derived from Molten Salt Method
Solar Cell Characteristic Studies on Metal Organic Framework/TiO2 Hybrid Solar Cell
In-situ Prepared 2D Covalent Organic Framework as a Photocatalyst in the Photocatalytic-Biocatalytic Attached System for Highly Selective L-Glutamate Production under Solar Light
Molecular Dynamics and FEM Modeling of Composites Having High Thermal Conductivity
Easy-Synthesis of BDA/ABDA Functionalized Hydrophilic Superparamagnetic Iron Oxide Nanoparticles for Magnetic-Hyperthermia Application
Electrochemical and Photocatalytic Properties of Green Nickel Oxide Nanomaterial Synthesized using Plectranthus Amboinicus Plant Leaf Extract
Copyright ©2010-2020 VBRI Press
Full Article