Ferrites; microwave synthesis; XRD; FTIR; SEM. Ferrites; microwave synthesis; XRD; FTIR; SEM.
1Department of Physics, Pandit Anant Ram Sanatan Dharam College, Baroh 176054, India
2Department of Physics, KRP Kanya Mahavidyalaya, Islampur 415409, India
3Department of Electronics, Shivaji University, Kolhapur 416004, India
Adv. Mater. Lett., 2013, Current Issue, 4 (5), pp 373-377
Publication Date (Web): Feb 23, 2013
Copyright © IAAM-VBRI Press
Powder diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy were used to characterize the spinel structure of nanocrystalline Ferrites with composition Mn1-xZnxFe2O4 (x = 0.2, 0.4, 0.6 and 0.8) prepared by oxalate coprecipitation technique and followed by microwave heating of precursors. Effect of composition on the lattice constant, x-ray density, crystallite size was studied. Crystallite size and x-ray density increases with increase in Zinc content. The face centered cubic spinel structure has undergone deviation from ideality. A correlation exists between splitting of infrared absorption bands and lowering of composition dependent crystalline symmetry. This preparation technique could be used for synthesis of materials which use microwave transparent precursors.
Ferrites, microwave synthesis, XRD, FTIR, SEM.