The cover photo of July 2019 issue is dedicated to the 41st anniversary of the first reported synthetic approach of dendritic hyperbranched structure. The cover photo adopted from the Valer et al., where they reported the preparation of dendritic hyperbranched copolymers based on bis(hydroxyl methyl) propionic acid polyester and studied the architecture - behavior - properties relationship. Dendritic structures are known for their perfect chemical definition, highly dense structure, and a well-defined number of surface functionalities. The soft multifunctional modifications could be compliant to valuable flexibility for embedding different chemical moieties on the surface either within the structure or at the core.
Architecture - behaviour - properties relationship in Star-shaped MPA-PMMA and MPA-PS hyper-branched copolymers
Gabriel Ríos Valer, Gisela Díaz, Juan M Giussi*, Marcelo Ceolín
Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA) - Departamento de Química - Facultad de Ciencias Exactas - Universidad Nacional de La Plata - CONICET, 1900 La Plata - Argentina
Adv. Mater. Lett., 2019, 10 (7), pp 476-483
DOI: 10.5185/amlett.2019.2224
Publication Date (Web): Jan 14, 2019
Copyright © 2019 VBRI Press
E-mail: jmgiussi@inifta.unlp.edu.ar
The molecular architecture of polymers is a crucial feature in the moment of think the relationship between properties and applications. The same polymer can present important differences according to its architecture and leads to different possible applications. In this paper, we describe the well preparation of hyperbranched copolymers based on bis (Hydroxyl-Methyl) propionic acid polyester (MPA). The co-monomers introduced via atom transfer radical polymerization were methyl methacrylate (MMA) and styrene (St). In order to study the effect of confinement, linear PMMA and PSt have been prepared, and moreover different levels of branching of each polymer were prepared. The synthesised star PMPA-PMMA and PMPA-PSt copolymers have been characterized and identified by infrared spectroscopy and nuclear magnetic resonance spectroscopy. Thermal transitions in solid state were studied using differential scanning calorimetry, and the thermal stability was evaluated by thermogravimetric analysis. Finally, solution properties have been evaluated thought Dynamic Light Scattering. Our results, obtained by a meticulous and systematic comparative study, showed a clear tendency between architectural level and thermal properties. Moreover, properties in solution revealed interesting response due to the modification of solvent nature. © VBRI Press.
Star-shaped hyperbranched copolymers with different generation levels, thermal characterization, solution properties.
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