Single Oriented CeO2 Buffer Layer Deposition On Biaxially Textured Ni-W Substrate By RF Magnetron Sputtering

K.M.K. Srivatsa, Preetam Singh*, Sourav Das

Physics of Energy Harvesting Division, Council of Scientific & Industrial Research (CSIR) - National Physical Laboratory,  Dr. K.S. Krishnan Marg, New Delhi 110012, India

Adv. Mater. Lett., 2015, 6 (10), pp 883-887

DOI: 10.5185/amlett.2015.5884

Publication Date (Web): Sep 18, 2015

E-mail: singhp@mail.nplindia.org

Abstract


Considerable attention has been gained on the deposition of CeO2 thin films with (200) single orientation as hetero-epitaxial buffer layer on (200) oriented biaxially textured flexible Ni substrates, in the fabrication of superconductor and semiconducting epitaxial thin films for device applications. In this work we have deposited (200) oriented CeO2 thin films on biaxially textured Ni-W substrate in a single-step process by RF magnetron sputtering, using CeO2 target. X-ray diffraction analysis shows that for the CeO2 thin film deposited at RF sputtering power below 200 W and for the substrate temperature of 700 oC, the film assumes single (200) orientation. For the substrate temperature below 700 oC and RF sputtering powers above 200 W the film shows polycrystalline nature with (111) and (200) orientations. The Raman spectrum of single oriented (200) CeO2 thin film shows only one sharp peak at about 464 cm-1 corresponds to the presence of F2g mode of CeO2. The ellipsometry studies reveal the value refractive index and optical band gap of single oriented film as 2.52 and 3.41 eV, respectively.

Keywords

CeO2 buffer layer, RF magnetron sputtering, XRD, Raman spectrum, optical properties.

Upcoming Congress

Knowledge Experience at Sea TM