Frequency And Temperature Dependent Impedance Study In 50% BaTiO3- 50% La0.7Sr0.3MnO3 Nanocomposite

Department of Physics, University of Kalyani, Kalyani 741235, West Bengal, India

Adv. Mater. Lett., 2014, 5 (7), pp 384-388

DOI: 10.5185/amlett.2014.05552

Publication Date (Web): Apr 27, 2014

Copyright © IAAM-VBRI Press

E-mail: sudipta.pal@rediffmail.com

Abstract

We report the impedance spectroscopy (IS) behavior of the ferroelectric- ferromagnetic (50% BaTi _O3-50% La_0.7Sr_0.3MnO₃) nano-composite prepared by sol-gel method. Frequency and temperature dependence of the complex impedance and conductivity has been measured over the temperature range 310 K-430 K. A distribution of relaxation times and decentralization of the semicircle has been observed from the Cole–Cole plots of real and imaginary parts of the complex impedance. Non-Debye type relaxation has been observed in the investigated composite system. An equivalent circuit has been constructed to describe the IS. Interestingly, a typical universal dielectric response in the frequency-dependent conductivity at different temperature has been found. The frequency dependent ac conductivity at different temperature indicates that the conduction process is thermally activated. The activation energy has been obtained from the Arrhenius fitting. The obtained dc conductivity showed that the system undergoes a positive temperature coefficient resistance (PTCR) to negative temperature coefficient resistance (NTCR) near 350 K. The results would help to understand deeply the relaxation process in these types of materials.

Keywords

Composite, impedance, AC conductivity, relaxation process