1Department of Physics, Institute of Technical Education and Research, SOA University, BBSR, India
2Department of Physics, Jupiter Science College, BBSR, India
3Department of Physics, KMBB College of Engineering and Technology, BBSR, India
Adv. Mater. Lett., 2012, 3 (1), pp 8-14
DOI: 10.5185/amlett.2011.4252
Publication Date (Web): Apr 10, 2012
Copyright © IAAM-VBRI Press
E-mail: prdas63@gmail.com, prdas@iter.ac.in
Complex impedance analysis of new tungsten bronze ferroelectric vanadates, Na2Pb2R2W2Ti4V4O30 (R = Gd, Eu), was carried out on samples prepared relatively at low temperature using a mixed-oxide technique. The formation of the materials under the reported conditions has been confirmed by an X-ray diffraction technique. A preliminary structural analysis exhibits orthorhombic crystal structure of the materials at room temperature. The electrical properties of the materials have been studied using ac impedance spectroscopy technique. Detailed studies of impedance and related parameters exhibit that the electrical properties of the materials are strongly dependent on temperature, and bear a good correlation with their microstructures. The temperature dependence of electrical relaxation phenomenon in the materials has been observed. The bulk resistance, evaluated from complex impedance spectra, is found to decrease with rise in temperature, exhibiting a typical negative temperature co-efficient of resistance (NTCR) – type behavior similar to that of semiconductors. A small contribution of grain boundary effect was also observed. The complex electric modulus analysis indicates the possibility of hopping conduction mechanism in the system with non-exponential type of conductivity relaxation. The ac conductivity spectra exhibit a typical signature of an ionic conducting system, and are found to obey Jonscher’s universal power law.
Electronic material, ceramics, impedance analysis, bulk resistance, electric modulus analysis
Water and Sanitation Management: During and after COVID-19 Pandemic
Polymeric Energy Materials: Development and Challenges
Influence of Different Copolymer Based Compatibilizers on Performance of Pristine and Recycled PP/PE blends
Bio Ceramics: New Material from Mangrove Bark
Hybrid Physical Chemical Vapour Deposition (HPCVD) of Superconducting MgB2 Thin Films on three Dimensional Copper Substrates
Photoinduced Electron Transfer Reactions of tris(4,4’-dimethoxy-2,2’-bipyridyl)ruthenium(II)cation with Quinones in Aqueous Medium
A Comparative Study of Green Synthesized AgNPs using Carissa Carandas and Nerium indicum Leaves and its Activities against Selected Human Pathogens and MCF 7 Cell
Design and Modelling of Carbon Fiber Grid Structure based Carbon/Epoxy Composites for Enhanced Microwave Absorbing Properties
Elaboration and Characterization of Macroporous Bioceramics using Polymeric Sponge Replication Method
Advanced Healthcare Biomaterials
Piezoelectric Alternative Energy Sources as a Part of the Global Energy Concerns – Future Prospects in the Science and Market
Rectify the Injury-Induced Microenvironment Imbalance in Peripheral Nerve Repair
A Mini Review on Biodegradable Magnesium Alloy Vascular Stent
Prospective Applications of Marine Oriented Materials in the Repair of Peripheral Nerve Injury
Design and Implementation of Dynamic FPAA Based Interface Circuit for Thin Film Lead-Free Piezoelectric Sensors
An Аpproach for Nanostructuring of Piezoelectric Materials by Template-assisted Growth in Porous Aluminum Oxide
Study of Sputtered Barium Strontium Titanate Films for Energy Harvesting Applications
The Effect of Bias on Properties of DLC Coatings for Artificial Joints
Fabrication of Tens-micron-sized Functionalized Polystyrene Microspheres for Utilization in Chiral Drug Isolation
Copyright ©2010-2020 VBRI Press
Full Article